diff --git a/changes/2073-PrettyWood.md b/changes/2073-PrettyWood.md
new file mode 100644
index 0000000..397fc78
--- /dev/null
+++ b/changes/2073-PrettyWood.md
@@ -0,0 +1 @@
+fix: keep the order of the fields when `validate_assignment` is set
\ No newline at end of file
diff --git a/pydantic/main.py b/pydantic/main.py
index 22a18dd..3d57b1b 100644
--- a/pydantic/main.py
+++ b/pydantic/main.py
@@ -384,14 +384,14 @@ class BaseModel(Representation, metaclass=ModelMetaclass):
 
             known_field = self.__fields__.get(name, None)
             if known_field:
-                original_value = self.__dict__.pop(name)
-                try:
-                    value, error_ = known_field.validate(value, self.__dict__, loc=name, cls=self.__class__)
-                    if error_:
-                        raise ValidationError([error_], self.__class__)
-                except Exception:
-                    self.__dict__[name] = original_value
-                    raise
+                # We want to
+                # - make sure validators are called without the current value for this field inside `values`
+                # - keep other values (e.g. submodels) untouched (using `BaseModel.dict()` will change them into dicts)
+                # - keep the order of the fields
+                dict_without_original_value = {k: v for k, v in self.__dict__.items() if k != name}
+                value, error_ = known_field.validate(value, dict_without_original_value, loc=name, cls=self.__class__)
+                if error_:
+                    raise ValidationError([error_], self.__class__)
                 else:
                     new_values[name] = value
 
diff --git a/tests/test_validators.py b/tests/test_validators.py
index 9097c17..62a68b0 100644
--- a/tests/test_validators.py
+++ b/tests/test_validators.py
@@ -5,7 +5,7 @@ from typing import Dict, List, Optional, Tuple
 
 import pytest
 
-from pydantic import BaseModel, ConfigError, Extra, ValidationError, errors, validator
+from pydantic import BaseModel, ConfigError, Extra, Field, ValidationError, errors, validator
 from pydantic.class_validators import make_generic_validator, root_validator
 from pydantic.typing import Literal
 
@@ -1162,7 +1162,8 @@ def test_field_that_is_being_validated_is_excluded_from_validator_values(mocker)
 
     class Model(BaseModel):
         foo: str
-        bar: str
+        bar: str = Field(alias='pika')
+        baz: str
 
         class Config:
             validate_assignment = True
@@ -1170,12 +1171,27 @@ def test_field_that_is_being_validated_is_excluded_from_validator_values(mocker)
         @validator('foo')
         def validate_foo(cls, v, values):
             check_values({**values})
+            return v
 
-    model = Model(foo='foo_value', bar='bar_value')
+        @validator('bar')
+        def validate_bar(cls, v, values):
+            check_values({**values})
+            return v
+
+    model = Model(foo='foo_value', pika='bar_value', baz='baz_value')
     check_values.reset_mock()
 
+    assert list(dict(model).items()) == [('foo', 'foo_value'), ('bar', 'bar_value'), ('baz', 'baz_value')]
+
     model.foo = 'new_foo_value'
-    check_values.assert_called_once_with({'bar': 'bar_value'})
+    check_values.assert_called_once_with({'bar': 'bar_value', 'baz': 'baz_value'})
+    check_values.reset_mock()
+
+    model.bar = 'new_bar_value'
+    check_values.assert_called_once_with({'foo': 'new_foo_value', 'baz': 'baz_value'})
+
+    # ensure field order is the same
+    assert list(dict(model).items()) == [('foo', 'new_foo_value'), ('bar', 'new_bar_value'), ('baz', 'baz_value')]
 
 
 def test_exceptions_in_field_validators_restore_original_field_value():